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Synfacts 2025; 21(07): 680
DOI: 10.1055/a-2601-4770
DOI: 10.1055/a-2601-4770
Synthesis of Materials and Unnatural Products
BN-Embedded Terrylene Diimides
Zhao K,
Xu Y-C,
Zeng J-C,
Qu Y-K,
Wang J-Y *,
Pei J *.
Peking University, Beijing, P. R. China
A Modular Approach toward BN-Embedded Terrylene Diimides.
Angew. Chem. Int. Ed. 2025;
64: e202503571
DOI: 10.1002/anie.202503571
A Modular Approach toward BN-Embedded Terrylene Diimides.
Angew. Chem. Int. Ed. 2025;
64: e202503571
DOI: 10.1002/anie.202503571
Keywords
BN-embedded terrylenes - electronic properties - optoelectronic devices - aromatic dicarboximides
Significance
Polycyclic aromatic hydrocarbons incorporating B/N atoms attract much attention because of their modified electronic and supramolecular properties. A set of terrylene diimides (TDI) with B/N embedded at different positions are synthesized.
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Comment
The incorporation of B/N atoms is shown to bestow induced dipole moment, lowered aromaticity and near-infrared fluorescence, as well as better electron-transporting semiconducting performance.
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Publication History
Article published online:
23 June 2025
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