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Synthesis 1985; 1985(9): 846-849
DOI: 10.1055/s-1985-31362
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γ-Substituted Secondary Organoalkaline Compounds and their Chlorinated Precursors: Synthetic Applications

José Barluenga* , Josefa Flórez, Miguel Yus
  • *Departamento de Química Orgánica, Facultad de Química, Universidad de Oviedo, 33071 Oviedo, Spain
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Publikationsdatum:
27. September 2002 (online)

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The prepartion of γ-functionalised secondary organolkaline metal compounds starting from methyl 3-chlorobutanoate (obtained by addition of hydrogen chloride to commercially available methyl trans-2-butenoate) is described. Reactions of these metallated compounds with suitable electrophilic reagents leads to a variety of tertiary alcohol derivatives.