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DOI: 10.1055/s-0030-1258083
Palladium-Catalyzed Heck-Type Coupling of Allyl Esters: β-Hydride versus β-Acetoxy Elimination
Publication History
Publication Date:
10 June 2010 (online)

Abstract
This account presents recent progress in palladium-catalyzed Heck-type reactions of allyl esters with aryl halides, arylmetallic reagents, or arenes. Many improvements have been achieved to control the regioselectivity of β-hydride or β-acetoxy elimination.
1 Introduction
2 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Aryl Halides
3 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Organometallic Reagents
4 Palladium-Catalyzed Heck-Type Coupling of Allyl Esters with Arenes via Aromatic C-H Activation
5 Other Transition Metal Catalyzed Heck-Type Reactions of Allyl Esters
6 Conclusion
Key words
transition-metal catalysis - allyl esters - Heck-type reactions - β-eliminations - couplings
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